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Photo Forum / Film Photography / Darkroom / April 2006

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Sometimes I want to use the old fim.

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Cheesehead - 16 Apr 2006 13:52 GMT
Bu it may be fogged.  Some of my Plux-X is age-fogged.
I know it can't be eliminated, but can it be dealt with to any degree?
Would these compensations help:

1. Don't use a fresh developer.  That often adds to fog by developing
every little detail.
2. Print @ grade 4 to reduce the fog effect.  Depending on how bad it
is, at least.

Collin
Mark Cassino - 16 Apr 2006 17:40 GMT
I had several expired rolls of Plus-X in both 120 and 35mm format that I
used up last year. I tried D76 1:1 and HCC 100 Dil H and Agfa Rodinal 1:50.
Hands down, the Rodinal produced far less fog, particularly noticeable in
the 120 film, where the fogging was barely noticeable. After using it, I
quit with the other developers (for the expired Plus-X).

Unfortunately, Agfa Rodinal is no longer made and would be hard to find.

- MCC

- - - - - - - - - - - - - - - - - - - -
Mark Cassino Photography
Kalamazoo, MI
www.markcassino.com
- - - - - - - - - - - - - - - - - - - -

> Bu it may be fogged.  Some of my Plux-X is age-fogged.
> I know it can't be eliminated, but can it be dealt with to any degree?
[quoted text clipped - 6 lines]
>
> Collin
Peter Chant - 17 Apr 2006 00:15 GMT
> Unfortunately, Agfa Rodinal is no longer made and would be hard to find.

Hmm, www.silverprint.co.uk.  Look under developers.

"Back as if it never went away, now being produced by the German chemical
manufacturer a&o."

Signature

http://www.petezilla.co.uk

Tony Polson - 17 Apr 2006 18:46 GMT
>Unfortunately, Agfa Rodinal is no longer made and would be hard to find.

Not true.  Production of Rodinal has now been re-started by the
company that took over the production of Agfa minilab chemicals.  It
is produced in the same factory with the same people, same machines
and same ingredients.  

A range of (former-)Agfa darkroom chemicals will be available, alas
their are no plans to re-start the production of Agfa Scala developer.
Mark Cassino - 18 Apr 2006 23:46 GMT
Hey - that's great news!

I haven't been keeping current on what happened with the Agfa situation, but
I'm glad to hear Rodinal is back. I laid in a supply last fall but have been
using it sparingly - nice to know I can dip into it freely again.

Thanks for passing that along -

MCC

Signature

- - - - - - - - - - - - - - - - - - - -
Mark Cassino Photography
Kalamazoo, MI
www.markcassino.com
- - - - - - - - - - - - - - - - - - - -

>
>>Unfortunately, Agfa Rodinal is no longer made and would be hard to find.
[quoted text clipped - 6 lines]
> A range of (former-)Agfa darkroom chemicals will be available, alas
> their are no plans to re-start the production of Agfa Scala developer.
Toni Nikkanen - 19 Apr 2006 09:08 GMT
> I haven't been keeping current on what happened with the Agfa situation, but
> I'm glad to hear Rodinal is back. I laid in a supply last fall but have been
> using it sparingly - nice to know I can dip into it freely again.

I knew the Agfa stuff was going away, but wasn't getting too worried
as the local photo store still has loads of Rodinal, Agefix, Agepon
and other Agfa stuff on the shelf. They even told me they have lots of
Agfapan 100 in store so no worries about that for a while, either.

Just in case, I already asked a pharmacist friend if the ingredients
needed for making Rodinal are readily available; they are.
Mark Cassino - 20 Apr 2006 01:19 GMT
From: "Toni Nikkanen" <toni@tuug.fi>

Sent: Wednesday, April 19, 2006 4:08 AM

> I knew the Agfa stuff was going away, but wasn't getting too worried
> as the local photo store still has loads of Rodinal, Agefix, Agepon
[quoted text clipped - 3 lines]
> Just in case, I already asked a pharmacist friend if the ingredients
> needed for making Rodinal are readily available; they are.

Unfortunately, the local photo stores here have not stocked Rodinal for some
time. Even when Agfa was fully in business the local stores stocked only
Kodak and Ilford, and these days the inventory is getting thinner and
thinner. My only practical source for Rodinal  was via mail order, and even
then B&H would not ship it due to hazardous materials rules. Adorama and
others would ship it, but would apply a surcharge due to the hazmat issue..

I took a look at ebay and see that people are selling it there, and I also
noticed JandCPhoto.com had it in stock a few weeks ago, though it was not
there today (the original R09 Rodinal is there.) For now I can just start
using my stockpile and wait and see what happens in the future!

Thanks again -

MCC

Signature

- - - - - - - - - - - - - - - - - - - -
Mark Cassino Photography
Kalamazoo, MI
www.markcassino.com
- - - - - - - - - - - - - - - - - - - -

>
>> I haven't been keeping current on what happened with the Agfa situation,
[quoted text clipped - 10 lines]
> Just in case, I already asked a pharmacist friend if the ingredients
> needed for making Rodinal are readily available; they are.
Rod Smith - 19 Apr 2006 16:37 GMT
>>Unfortunately, Agfa Rodinal is no longer made and would be hard to find.
>
> Not true.  Production of Rodinal has now been re-started by the
> company that took over the production of Agfa minilab chemicals.  It
> is produced in the same factory with the same people, same machines
> and same ingredients.  

In addition, there are several very similar alternatives. "R09" (sold by
Calbe and Foma, at least) is supposed to be an older version of the
Rodinal formula (circa WWII) and Photographer's Formulary has something as
well, but it seems to come as powdered chemicals that you mix yourself.
Along those lines, several formulas have been published for "Rodinal-like"
developers. I don't know which of these is closest to what Agfa sold as
Rodinal and that is now or will soon be sold under the A&O label, though.
Ingredients can be bought from Photographer's Formulary and other
photochemistry suppliers. A few items can be bought from other sources,
too. Something very like Rodinal can be made from acetaminophen (Tylenol),
lye, and one or two other ingredients. (Acetaminophen is chemically
related to para aminophenol, the developing agent in Rodinal; the
acetaminophen is converted into para aminophenol when these formulas are
mixed.)

In sum, Rodinal isn't gone and isn't likely to vanish any time soon, even
if A&O decides to get out of the Rodinal game. At worst, Rodinal
afficionados will need to find another source of supply or mix their own.
Those who are VERY fussy may need to experiment to find the product or
formula they like best. In the short term, supplies of Agfa Rodinal, under
the A&O brand name, seem secure.

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Rod Smith, rodsmith@rodsbooks.com
http://www.rodsbooks.com
Author of books on Linux, FreeBSD, and networking

Geoffrey S. Mendelson - 19 Apr 2006 17:11 GMT
>Something very like Rodinal can be made from acetaminophen (Tylenol),
> lye, and one or two other ingredients. (Acetaminophen is chemically
> related to para aminophenol, the developing agent in Rodinal; the
> acetaminophen is converted into para aminophenol when these formulas are
> mixed.)

If you have any pointers to these formulas please post them.

I can get the generic eqivalent of tylenol (called Akamol here) and Lye
based drain cleaner, would they do?

TIA.

Geoff.

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Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com  N3OWJ/4X1GM
IL Voice: (07)-7424-1667  IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838
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Geoffrey S. Mendelson - 19 Apr 2006 23:30 GMT
>>Something very like Rodinal can be made from acetaminophen (Tylenol),
>> lye, and one or two other ingredients. (Acetaminophen is chemically
>> related to para aminophenol, the developing agent in Rodinal; the
>> acetaminophen is converted into para aminophenol when these formulas are
>> mixed.)

I wrote:

> If you have any pointers to these formulas please post them.
>
> I can get the generic eqivalent of tylenol (called Akamol here) and Lye
> based drain cleaner, would they do?

To extend my orignal posting, I found the formula with a web search,

I'm not sure about the sodium hydroxide though. I can get lye based drain
cleaner, but I'm not sure how pure it is. For example it is illegal to
sell ammonia based cleaning products here.  

Is it possible to produce the same formula with a less caustic and more
easily available substance such as sodium bicarbonate? I can get that at
a pharmacy in 100 gram  bottles and if luck is with me I can get 250 grams
(about 8 ounces) of Arm and Hammer baking soda in a plastic bottle.

Sodium sulfite is something I would have to get at a photo store in Tel Aviv
(I'm in Jerusalem).

As things go, the generic tylenol you buy for $10 for 300 "caplets" is
probably made by Teva in Israel (they are the world's largest maker of
generic drugs), but I pay about half of that for 50.

Geoff.
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Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com  N3OWJ/4X1GM
IL Voice: (07)-7424-1667  IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838
Visit my 'blog at http://geoffstechno.livejournal.com/

Rod Smith - 20 Apr 2006 03:05 GMT
>>Something very like Rodinal can be made from acetaminophen (Tylenol),
>> lye, and one or two other ingredients. (Acetaminophen is chemically
[quoted text clipped - 3 lines]
>
> If you have any pointers to these formulas please post them.

I've run across several, including:

http://www.apug.org/forums/showthread.php?p=218374#post218374
http://www.apug.org/forums/showthread.php?t=22301&page=4&pp=10

The second one (in the last post on the page) is claimed to work with
Rodinal times and dilutions. Note that I've not used this one, although I
did use another one. I've not included a link to that one because it
worked OK with some films but not with others; it was somebody's early
experiment and not really a close equivalent to Rodinal.

> I can get the generic eqivalent of tylenol (called Akamol here) and Lye
> based drain cleaner, would they do?

The generic equivalent of Tylenol will probably be fine. With any such
drug, you'll be adding unknown substances (fillers and whatnot) into the
developer. With luck these will be photographically inert, and my and
others' experiments suggest that they often are, but I can't promise that.
(FWIW, I used store-brand acetaminophen tablets in my brief experiment
with this type of developer.)

For lye, that's tougher. In the US, a product called Red Devil Lye is sold
as a drain cleaner and is pure enough for this purpose, although it's
getting hard to find, apparently because lye is an ingredient in
methamphetamines. Most lye-based drain cleaners include metal shavings or
other things that make the products unsuitable for use in film developers
(or illegal drugs). Substances such as sodium bicarbonate aren't suitable
substitutes because, as I understand it, part of the reason for the lye in
acetaminophen-based developers is that the hydroxide in the lye reacts
with the acetaminophen to create para aminophenol. My understanding is
that sodium bicarbonate, sodium carbonate, borax, etc., won't react with
the acetaminophen, or at least not in a way that generates para
aminophenol. I'm not a chemist, though, so my understanding of this is
limited at best and may be substantially wrong.

You might want to check out hobbyist soap-making outlets in your area. Lye
(and potassium hydroxide, which might work in such formulas, although I've
not tested this) is used in soap-making, so hobby shops with soap-making
supplies should have it.

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Rod Smith, rodsmith@rodsbooks.com
http://www.rodsbooks.com
Author of books on Linux, FreeBSD, and networking

Geoffrey S. Mendelson - 20 Apr 2006 11:21 GMT
Thanks for your reply. It was very helpful.

> You might want to check out hobbyist soap-making outlets in your area. Lye
> (and potassium hydroxide, which might work in such formulas, although I've
> not tested this) is used in soap-making, so hobby shops with soap-making
> supplies should have it.

Having lived most of my life in the U.S. I understand your suggestion,
but the average Israeli would ask "what's a hobby" and why would a shop
sell them?

With an avarage monthly income of about $1,000 after taxes, most people
never have time or money for a hobby.

Thanks,

Geoff.

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Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com  N3OWJ/4X1GM
IL Voice: (07)-7424-1667  IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838
Visit my 'blog at http://geoffstechno.livejournal.com/

Nicholas O. Lindan - 17 Apr 2006 01:08 GMT
> Some of my Plux-X is age-fogged. [what to do?']
> 1. Don't use a fresh developer??

Use fresh developer -- D=76 1:1 1-shot, Rodinal, etc.

Best bet is benzotriazole: 10g from B&H, 2 pints of
90%+ isopropyl alcohol.

o Disolve the 10g in a bottle of isopr. for a 2%
  solution

o Pour out ~25ml out of the second bottle of
  isopr. and add 25ml of the 2% in its place:
  this makes a 0.1% solution.  10ml contains
  10mg. of benz.

Working range is 10-100mg/l.  To a 16oz
tank of developer add 2.5 - 25ml of the 0.1%.

Development times will be longer.
Richard Knoppow - 17 Apr 2006 03:27 GMT
> Bu it may be fogged.  Some of my Plux-X is age-fogged.
> I know it can't be eliminated, but can it be dealt with to
[quoted text clipped - 9 lines]
>
> Collin

  Uniform fog simply increases printing time and effective
speed. Increase exposure to compensate. The use of
Benzotriazole in the developer is very effective in reducing
age fog but it also reduces the speed so there may not be
much advantage. Bromide also reduces fog but generally have
more effect on film speed than Benzotriazole.
  I have had success using very old Plus-X Pan sheet film
by processing in D-76 1:1 with about 2 grams of Potassium
Bromide added per liter. The film was rated at ISO-125, I
shot it at around EI-32. OTOH, I also have some Agfa Agfapan
100 of about the same age. This is so fogged that bromide
doesn't help.

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---
Richard Knoppow
Los Angeles, CA, USA
dickburk@ix.netcom.com

 
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