Photo Forum / Film Photography / Darkroom / April 2006
Sometimes I want to use the old fim.
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Cheesehead - 16 Apr 2006 13:52 GMT Bu it may be fogged. Some of my Plux-X is age-fogged. I know it can't be eliminated, but can it be dealt with to any degree? Would these compensations help:
1. Don't use a fresh developer. That often adds to fog by developing every little detail. 2. Print @ grade 4 to reduce the fog effect. Depending on how bad it is, at least.
Collin
Mark Cassino - 16 Apr 2006 17:40 GMT I had several expired rolls of Plus-X in both 120 and 35mm format that I used up last year. I tried D76 1:1 and HCC 100 Dil H and Agfa Rodinal 1:50. Hands down, the Rodinal produced far less fog, particularly noticeable in the 120 film, where the fogging was barely noticeable. After using it, I quit with the other developers (for the expired Plus-X).
Unfortunately, Agfa Rodinal is no longer made and would be hard to find.
- MCC
- - - - - - - - - - - - - - - - - - - - Mark Cassino Photography Kalamazoo, MI www.markcassino.com - - - - - - - - - - - - - - - - - - - -
> Bu it may be fogged. Some of my Plux-X is age-fogged. > I know it can't be eliminated, but can it be dealt with to any degree? [quoted text clipped - 6 lines] > > Collin Peter Chant - 17 Apr 2006 00:15 GMT > Unfortunately, Agfa Rodinal is no longer made and would be hard to find. Hmm, www.silverprint.co.uk. Look under developers.
"Back as if it never went away, now being produced by the German chemical manufacturer a&o."
 Signature http://www.petezilla.co.uk
Tony Polson - 17 Apr 2006 18:46 GMT >Unfortunately, Agfa Rodinal is no longer made and would be hard to find. Not true. Production of Rodinal has now been re-started by the company that took over the production of Agfa minilab chemicals. It is produced in the same factory with the same people, same machines and same ingredients.
A range of (former-)Agfa darkroom chemicals will be available, alas their are no plans to re-start the production of Agfa Scala developer.
Mark Cassino - 18 Apr 2006 23:46 GMT Hey - that's great news!
I haven't been keeping current on what happened with the Agfa situation, but I'm glad to hear Rodinal is back. I laid in a supply last fall but have been using it sparingly - nice to know I can dip into it freely again.
Thanks for passing that along -
MCC
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> >>Unfortunately, Agfa Rodinal is no longer made and would be hard to find. [quoted text clipped - 6 lines] > A range of (former-)Agfa darkroom chemicals will be available, alas > their are no plans to re-start the production of Agfa Scala developer. Toni Nikkanen - 19 Apr 2006 09:08 GMT > I haven't been keeping current on what happened with the Agfa situation, but > I'm glad to hear Rodinal is back. I laid in a supply last fall but have been > using it sparingly - nice to know I can dip into it freely again. I knew the Agfa stuff was going away, but wasn't getting too worried as the local photo store still has loads of Rodinal, Agefix, Agepon and other Agfa stuff on the shelf. They even told me they have lots of Agfapan 100 in store so no worries about that for a while, either.
Just in case, I already asked a pharmacist friend if the ingredients needed for making Rodinal are readily available; they are.
Mark Cassino - 20 Apr 2006 01:19 GMT From: "Toni Nikkanen" <toni@tuug.fi>
Sent: Wednesday, April 19, 2006 4:08 AM
> I knew the Agfa stuff was going away, but wasn't getting too worried > as the local photo store still has loads of Rodinal, Agefix, Agepon [quoted text clipped - 3 lines] > Just in case, I already asked a pharmacist friend if the ingredients > needed for making Rodinal are readily available; they are. Unfortunately, the local photo stores here have not stocked Rodinal for some time. Even when Agfa was fully in business the local stores stocked only Kodak and Ilford, and these days the inventory is getting thinner and thinner. My only practical source for Rodinal was via mail order, and even then B&H would not ship it due to hazardous materials rules. Adorama and others would ship it, but would apply a surcharge due to the hazmat issue..
I took a look at ebay and see that people are selling it there, and I also noticed JandCPhoto.com had it in stock a few weeks ago, though it was not there today (the original R09 Rodinal is there.) For now I can just start using my stockpile and wait and see what happens in the future!
Thanks again -
MCC
 Signature - - - - - - - - - - - - - - - - - - - - Mark Cassino Photography Kalamazoo, MI www.markcassino.com - - - - - - - - - - - - - - - - - - - -
> >> I haven't been keeping current on what happened with the Agfa situation, [quoted text clipped - 10 lines] > Just in case, I already asked a pharmacist friend if the ingredients > needed for making Rodinal are readily available; they are. Rod Smith - 19 Apr 2006 16:37 GMT >>Unfortunately, Agfa Rodinal is no longer made and would be hard to find. > > Not true. Production of Rodinal has now been re-started by the > company that took over the production of Agfa minilab chemicals. It > is produced in the same factory with the same people, same machines > and same ingredients. In addition, there are several very similar alternatives. "R09" (sold by Calbe and Foma, at least) is supposed to be an older version of the Rodinal formula (circa WWII) and Photographer's Formulary has something as well, but it seems to come as powdered chemicals that you mix yourself. Along those lines, several formulas have been published for "Rodinal-like" developers. I don't know which of these is closest to what Agfa sold as Rodinal and that is now or will soon be sold under the A&O label, though. Ingredients can be bought from Photographer's Formulary and other photochemistry suppliers. A few items can be bought from other sources, too. Something very like Rodinal can be made from acetaminophen (Tylenol), lye, and one or two other ingredients. (Acetaminophen is chemically related to para aminophenol, the developing agent in Rodinal; the acetaminophen is converted into para aminophenol when these formulas are mixed.)
In sum, Rodinal isn't gone and isn't likely to vanish any time soon, even if A&O decides to get out of the Rodinal game. At worst, Rodinal afficionados will need to find another source of supply or mix their own. Those who are VERY fussy may need to experiment to find the product or formula they like best. In the short term, supplies of Agfa Rodinal, under the A&O brand name, seem secure.
 Signature Rod Smith, rodsmith@rodsbooks.com http://www.rodsbooks.com Author of books on Linux, FreeBSD, and networking
Geoffrey S. Mendelson - 19 Apr 2006 17:11 GMT >Something very like Rodinal can be made from acetaminophen (Tylenol), > lye, and one or two other ingredients. (Acetaminophen is chemically > related to para aminophenol, the developing agent in Rodinal; the > acetaminophen is converted into para aminophenol when these formulas are > mixed.) If you have any pointers to these formulas please post them.
I can get the generic eqivalent of tylenol (called Akamol here) and Lye based drain cleaner, would they do?
TIA.
Geoff.
 Signature Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com N3OWJ/4X1GM IL Voice: (07)-7424-1667 IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838 Visit my 'blog at http://geoffstechno.livejournal.com/
Geoffrey S. Mendelson - 19 Apr 2006 23:30 GMT >>Something very like Rodinal can be made from acetaminophen (Tylenol), >> lye, and one or two other ingredients. (Acetaminophen is chemically >> related to para aminophenol, the developing agent in Rodinal; the >> acetaminophen is converted into para aminophenol when these formulas are >> mixed.) I wrote:
> If you have any pointers to these formulas please post them. > > I can get the generic eqivalent of tylenol (called Akamol here) and Lye > based drain cleaner, would they do? To extend my orignal posting, I found the formula with a web search,
I'm not sure about the sodium hydroxide though. I can get lye based drain cleaner, but I'm not sure how pure it is. For example it is illegal to sell ammonia based cleaning products here.
Is it possible to produce the same formula with a less caustic and more easily available substance such as sodium bicarbonate? I can get that at a pharmacy in 100 gram bottles and if luck is with me I can get 250 grams (about 8 ounces) of Arm and Hammer baking soda in a plastic bottle.
Sodium sulfite is something I would have to get at a photo store in Tel Aviv (I'm in Jerusalem).
As things go, the generic tylenol you buy for $10 for 300 "caplets" is probably made by Teva in Israel (they are the world's largest maker of generic drugs), but I pay about half of that for 50.
Geoff.
 Signature Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com N3OWJ/4X1GM IL Voice: (07)-7424-1667 IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838 Visit my 'blog at http://geoffstechno.livejournal.com/
Rod Smith - 20 Apr 2006 03:05 GMT >>Something very like Rodinal can be made from acetaminophen (Tylenol), >> lye, and one or two other ingredients. (Acetaminophen is chemically [quoted text clipped - 3 lines] > > If you have any pointers to these formulas please post them. I've run across several, including:
http://www.apug.org/forums/showthread.php?p=218374#post218374 http://www.apug.org/forums/showthread.php?t=22301&page=4&pp=10
The second one (in the last post on the page) is claimed to work with Rodinal times and dilutions. Note that I've not used this one, although I did use another one. I've not included a link to that one because it worked OK with some films but not with others; it was somebody's early experiment and not really a close equivalent to Rodinal.
> I can get the generic eqivalent of tylenol (called Akamol here) and Lye > based drain cleaner, would they do? The generic equivalent of Tylenol will probably be fine. With any such drug, you'll be adding unknown substances (fillers and whatnot) into the developer. With luck these will be photographically inert, and my and others' experiments suggest that they often are, but I can't promise that. (FWIW, I used store-brand acetaminophen tablets in my brief experiment with this type of developer.)
For lye, that's tougher. In the US, a product called Red Devil Lye is sold as a drain cleaner and is pure enough for this purpose, although it's getting hard to find, apparently because lye is an ingredient in methamphetamines. Most lye-based drain cleaners include metal shavings or other things that make the products unsuitable for use in film developers (or illegal drugs). Substances such as sodium bicarbonate aren't suitable substitutes because, as I understand it, part of the reason for the lye in acetaminophen-based developers is that the hydroxide in the lye reacts with the acetaminophen to create para aminophenol. My understanding is that sodium bicarbonate, sodium carbonate, borax, etc., won't react with the acetaminophen, or at least not in a way that generates para aminophenol. I'm not a chemist, though, so my understanding of this is limited at best and may be substantially wrong.
You might want to check out hobbyist soap-making outlets in your area. Lye (and potassium hydroxide, which might work in such formulas, although I've not tested this) is used in soap-making, so hobby shops with soap-making supplies should have it.
 Signature Rod Smith, rodsmith@rodsbooks.com http://www.rodsbooks.com Author of books on Linux, FreeBSD, and networking
Geoffrey S. Mendelson - 20 Apr 2006 11:21 GMT Thanks for your reply. It was very helpful.
> You might want to check out hobbyist soap-making outlets in your area. Lye > (and potassium hydroxide, which might work in such formulas, although I've > not tested this) is used in soap-making, so hobby shops with soap-making > supplies should have it. Having lived most of my life in the U.S. I understand your suggestion, but the average Israeli would ask "what's a hobby" and why would a shop sell them?
With an avarage monthly income of about $1,000 after taxes, most people never have time or money for a hobby.
Thanks,
Geoff.
 Signature Geoffrey S. Mendelson, Jerusalem, Israel gsm@mendelson.com N3OWJ/4X1GM IL Voice: (07)-7424-1667 IL Fax: 972-2-648-1443 U.S. Voice: 1-215-821-1838 Visit my 'blog at http://geoffstechno.livejournal.com/
Nicholas O. Lindan - 17 Apr 2006 01:08 GMT > Some of my Plux-X is age-fogged. [what to do?'] > 1. Don't use a fresh developer?? Use fresh developer -- D=76 1:1 1-shot, Rodinal, etc.
Best bet is benzotriazole: 10g from B&H, 2 pints of 90%+ isopropyl alcohol.
o Disolve the 10g in a bottle of isopr. for a 2% solution
o Pour out ~25ml out of the second bottle of isopr. and add 25ml of the 2% in its place: this makes a 0.1% solution. 10ml contains 10mg. of benz.
Working range is 10-100mg/l. To a 16oz tank of developer add 2.5 - 25ml of the 0.1%.
Development times will be longer.
Richard Knoppow - 17 Apr 2006 03:27 GMT > Bu it may be fogged. Some of my Plux-X is age-fogged. > I know it can't be eliminated, but can it be dealt with to [quoted text clipped - 9 lines] > > Collin Uniform fog simply increases printing time and effective speed. Increase exposure to compensate. The use of Benzotriazole in the developer is very effective in reducing age fog but it also reduces the speed so there may not be much advantage. Bromide also reduces fog but generally have more effect on film speed than Benzotriazole. I have had success using very old Plus-X Pan sheet film by processing in D-76 1:1 with about 2 grams of Potassium Bromide added per liter. The film was rated at ISO-125, I shot it at around EI-32. OTOH, I also have some Agfa Agfapan 100 of about the same age. This is so fogged that bromide doesn't help.
 Signature --- Richard Knoppow Los Angeles, CA, USA dickburk@ix.netcom.com
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