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Photo Forum / Film Photography / Darkroom / May 2005

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Some Questions about D76

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Graham Fountain - 31 Mar 2005 12:53 GMT
In the past I have always used Ilford LC29, purely because it is the only
developer that is stocked by the only local shop that sells this type of
stuff. Anyway, they've now stopped stocking developer, so I will be buying
developer online.  The place I am looking at online (www.vanbar.com.au)
doesn't stock LC29, so I've had a look at what they stock, and it appears
that D76 appears to offer the best price, as well as having the most readily
accessible development times for a variety of films. So, onto my
questions...
Am I correct that it ships as a powder?
If I buy the kit to make 1 US Gallon, do I have to mix the whole lot in one
hit, or is it ok to mix up small amounts at a time? I have a paterson
developing tank, normally develop 1 roll of 36 exp 35mm at a time, and it
needs 300ml, so I'd probably mix that amount if I could. Sometimes I will
shoot 5 rolls in a week, other weeks I may go 2 or 3 weeks without doing
any.
Even if I mix up the whole gallon, would you suggest using 300ml at a time
one shot, or would you suggest reusing developer? (it is certainly
economical enough for one shot).
Would you recommend mixing it 1:1 or using it stock? From what I can gather,
it still delivers the same capacity at 1:1, but allows longer developing
time. Is there any appreciable difference in negs developed stock compared
to 1:1, assuming both are developed the appropriate time.
Ilford ID11 is apparently the same as D76 - is there any of the above that
you would have different recommendations for when using ID11?
Thanks in advance for any help people can provide.
Martin Jangowski - 31 Mar 2005 13:25 GMT
> Am I correct that it ships as a powder?

Yes.

> If I buy the kit to make 1 US Gallon, do I have to mix the whole lot in one
> hit, or is it ok to mix up small amounts at a time? I have a paterson
> developing tank, normally develop 1 roll of 36 exp 35mm at a time, and it
> needs 300ml, so I'd probably mix that amount if I could. Sometimes I will
> shoot 5 rolls in a week, other weeks I may go 2 or 3 weeks without doing
> any.

Mix the whole volume (the "stock solution") and fill several brown glass
bottles to the brim. It should keep at least 6 month this way.

> Even if I mix up the whole gallon, would you suggest using 300ml at a time
> one shot, or would you suggest reusing developer? (it is certainly
> economical enough for one shot).

If you want consistent results and your usage isn't regular, forget
reusing developer. It is _much_ better to use fresh developer (even if
its a few month old) from a closed glass bottle to develop your films.
There are some photographers who fill small bottles with enough solution
for one film and store it this way.

> Would you recommend mixing it 1:1 or using it stock? From what I can gather,
> it still delivers the same capacity at 1:1, but allows longer developing
> time. Is there any appreciable difference in negs developed stock compared
> to 1:1, assuming both are developed the appropriate time.
> Ilford ID11 is apparently the same as D76 - is there any of the above that
> you would have different recommendations for when using ID11?

There isn't a real big difference between stock and 1+1. There are
people who claim that using stock solution gives a little finer grain
and 1+1 is sharper, but in fact you won't be able to see a difference
when shown two enlargements made with both methods. It depends on your
method of working if using stock solution makes sense... if you use
rotation, you could think about it. If you use a standard drum with
intermittend motion, it is much more economical to use 1+1 (or 1+3). You
should always use at least 100ml stock solution per film (that is a
135/36 or a 120). This will give 200ml solution 1+1 or 400ml 1+3 _per
film_! Do not overtax the developer, this is the cheapest part of the
whole game. One ruined film buys the next package of developer...

Martin
Graham Fountain - 05 Apr 2005 11:37 GMT
<snip>

> Mix the whole volume (the "stock solution") and fill several brown glass
> bottles to the brim. It should keep at least 6 month this way.

<snip>
> If you want consistent results and your usage isn't regular, forget
> reusing developer. It is _much_ better to use fresh developer (even if
> its a few month old) from a closed glass bottle to develop your films.
> There are some photographers who fill small bottles with enough solution
> for one film and store it this way.
I think that's what I'll do - I will soon be able to get hold of a number of
300ml glass bottles, so I'll fill them, then each bottle will do one roll of
film. At the price of the 3.8L kit, it will work out at under 50c per roll,
which is dirt cheap. The thing that through me off was in Kodak's tech sheet
about it, all the talk about replenishment etc. It is cheap enough for me to
use single shot, so that's what I'll do.
> There isn't a real big difference between stock and 1+1. There are
> people who claim that using stock solution gives a little finer grain
[quoted text clipped - 7 lines]
> film_! Do not overtax the developer, this is the cheapest part of the
> whole game. One ruined film buys the next package of developer...
Correct me if I'm wrong, but if stock will give a short developing
time(<5mins), I'd probably be better to use it 1:1 to get a longer time -
longer time means less proportional variation in things like pouring time,
and hence higher consistency - right?

> Martin
Rod Smith - 05 Apr 2005 20:18 GMT
> I will soon be able to get hold of a number of
> 300ml glass bottles, so I'll fill them, then each bottle will do one roll of
> film.

If you use it undiluted, yes (give or take a bit depending on your tank's
capacity). If you use it diluted, a 300ml bottle will hold enough to do
two rolls of film. (You should dilute the developer just before you use
it; don't store it diluted.)

> Correct me if I'm wrong, but if stock will give a short developing
> time(<5mins), I'd probably be better to use it 1:1 to get a longer time -
> longer time means less proportional variation in things like pouring time,
> and hence higher consistency - right?

Yes. Most photographers like developing times of ~10 minutes for those
reasons; that's a good compromise between time standing around turning a
cylinder upside down and accuracy in controlling the start and end times.

In another post, you wrote:

> One of my reasons for thinking D76 would be my best bet, is that there are
> published developing times for a wide variety of films, including pushed
> times also. while there is quite a bit of data for rodinal, it doesn't
> appear to be as widespread as the data for d76.

What's most important is the films you use on a regular basis. As to
sources of developing times, the most comprehensive I know of is the
Massive Dev Chart:

http://www.digitaltruth.com/devchart.html

Just skimming its D-76 and Rodinal sections, the latter seems ALMOST as
comprehensive as the former, but not quite. I'm not advocating the use of
Rodinal (I'm pretty new at this and have never used it myself), but there
does seem to be data for it for a good range of films. Personally, I'd
base my decision on other factors (availability, price, powder vs. liquid,
likely keeping time, general reputation, grain, acutance, effective film
speed, etc.).

Signature

Rod Smith, rodsmith@rodsbooks.com
http://www.rodsbooks.com
Author of books on Linux, FreeBSD, and networking

Rod Smith - 31 Mar 2005 17:45 GMT
> I've had a look at what they stock, and it appears
> that D76 appears to offer the best price, as well as having the most readily
> accessible development times for a variety of films.

First off, I'm still pretty new to B&W processing, but what I've done,
I've done with D76, and I asked these same questions myself, so....

I believe that D76 is the most popular B&W film developer in the world, so
you'll certainly find lots of information on it. Other developers are also
pretty popular, and each has its proponents.

Also, be aware that D76 is made (sometimes under other names) by several
companies. You might be able to save some money by buying a non-Kodak D76
-- but if it's Joe's Home-Brew Film Developer and Shoelace Company that
makes it, I'd be a bit concerned about quality control. ;-) You can even
find formulas for D76 and mix it up yourself. Note that the big
manufacturers often tweak the formula a bit to improve shelf life or
whatnot.

When computing price, be sure to figure in dilutions. For instance,
undiluted Rodinal is pretty expensive compared to a stock solution of D76,
but Rodinal is typically diluted 1:50 or thereabouts, whereas D76 is
usually diluted between 1:1 to 1:3.

> Am I correct that it ships as a powder?

Yes, at least for the Kodak variety. If you're looking for a developer
that ships as a liquid, HC110 is often recommended as a liquid developer
that produces results similar to D76. (There's a current thread on it in
this newsgroup.) Agfa Rodinal is another popular liquid developer, but
it's loved by some and hated by others. (Rodinal tends to enhance both
sharpness and grain.) The site you referenced sells a lot of Paterson
stuff, and I've seen good things written about Paterson FX39, but I get
the impression that it's not very popular. Ilford Ilfosol-S is in this
category, too. I've used none of these, though; I'm just throwing them out
as liquid developers I've seen discussed and that the site you mentioned
stocks.

> If I buy the kit to make 1 US Gallon, do I have to mix the whole lot in one
> hit, or is it ok to mix up small amounts at a time?

The most common advice is to mix it all up at once. The problem with
mixing smaller batches is that the bag contains several different
chemicals, which can separate out during shipment. If you mix just part of
the bag, you might not be getting the right proportion of various
chemicals.

OTOH, I've heard from people who do mix it up a bit at a time and say it
works. This seems to be much more common (and less likely to pose
problems) when you mix up your own developer. If you must mix up part of a
commercial bag, shake it up well before mixing. Given that the stock
solution has an official shelf life of 6 months in properly sealed
bottles, I'd recommend mixing it all up at once. The worst-case scenario
is that you'll only use part of it, but it's pretty inexpensive stuff, so
even if half of it goes to waste, it's not THAT big of a problem.

> Even if I mix up the whole gallon, would you suggest using 300ml at a time
> one shot, or would you suggest reusing developer? (it is certainly
> economical enough for one shot).
> Would you recommend mixing it 1:1 or using it stock?

My understanding is that undiluted D76 can be re-used, but few people do
it because it requires extending development time for each re-use and
makes the results less consistent. Instead, most people dilute it 1:1 or
greater and use the diluted working solution one-shot.

> Ilford ID11 is apparently the same as D76 - is there any of the above that
> you would have different recommendations for when using ID11?

My understanding is that Ilford ID11 ships in two bags rather than one, so
the mixing procedure is slightly different, but once it's mixed, it's
functionally identical to Kodak D76. (There may be some minor differences
in the tweaks each company gives its formulation, but nothing worth
worrying about, AFAIK.) I'd buy whichever costs less.

Signature

Rod Smith, rodsmith@rodsbooks.com
http://www.rodsbooks.com
Author of books on Linux, FreeBSD, and networking

dan.c.quinn@att.net - 31 Mar 2005 23:44 GMT
RE:Graham Fountain

Gigantic selection of chemistry, and , and, ... ; Vanbar.
A concentrate such as Rodinal or one of the many others they
carry is likely your best bet for longevity and economy. Dan
Graham Fountain - 05 Apr 2005 11:44 GMT
> RE:Graham Fountain
>
> Gigantic selection of chemistry, and , and, ... ; Vanbar.
> A concentrate such as Rodinal or one of the many others they
> carry is likely your best bet for longevity and economy. Dan
One of my reasons for thinking D76 would be my best bet, is that there are
published developing times for a wide variety of films, including pushed
times also. while there is quite a bit of data for rodinal, it doesn't
appear to be as widespread as the data for d76.
C. Falise - 05 Apr 2005 07:16 GMT
> In the past I have always used Ilford LC29, purely because it is the only
> developer that is stocked by the only local shop that sells this type of
[quoted text clipped - 21 lines]
> you would have different recommendations for when using ID11?
> Thanks in advance for any help people can provide.

lots of questions -
i've been working with d76 ( and sometimes hc110) for about 20 years.
i've found it to be highly stable and reliable when used freshly mixed 1:3
as well as storing 1:1 for a few weeks.
rod had some very useful information, so i will not add too much to it.
IMHO,  if you do not shoot lots and lots of film on a regular basis, d76 is
a good safe bet.  in the age of film photographers becoming dinosaurs (i am
one of them), it is one of the few b/w film developers available at a decent
price without shipping liquids or using more complex, less stable chemistry.
i will re-emphasize one thing - shake up the powder very well and let it sit
for 20 mins or so, then mix up what you need -  i mix up 1/2 gallon at a
time.  i have used patterson reels.  i prefer stainless steel (old school to
the death, i guess).  same idea, different mechanism.   i usually develop
1-2 reels at a time (medium format), then none for a few weeks at least.  if
you are this kind of photographer, then d76 is the way to go.  i dilute 1:3
because it gives me more control over processing times, but if you are
impatient, or under deadline, then 1:1 at shorter times works quite well, if
you don't need super-fine grain.
another note - do not re-use it unless it's within 48 hrs or so of mix
unless it is in a really airtight bottle preferably with less than 10% air.
it takes longer and longer to develop and it's les predictable.  it's not
good after it sits for more than 10 days or so... this refers to stock
solutions.
good luck-
-christina
DEAN HOFFMAN - 03 May 2005 00:31 GMT
ID11 and D76 are identical. This formula has been used for many years and
always rates as one of the best. The 1 to 1 solution offers greater
sharpness and better contrast control. In addition, your development is
consistant because the developer is always the same - fresh. Unfortunately,
the development times are long - especially for people used to Rodinal or
HC110. The life of your gallon of deveoper can be several months if you are
able to keep air contact to a minimum. I've used D76 with replenisher doing
4x5 work for shorter times, but for smaller formats, you can't beat the
quality of D76 1 to 1.
> In the past I have always used Ilford LC29, purely because it is the only
> developer that is stocked by the only local shop that sells this type of
[quoted text clipped - 21 lines]
> you would have different recommendations for when using ID11?
> Thanks in advance for any help people can provide.
John - 03 May 2005 05:29 GMT
>ID11 and D76 are identical. This formula has been used for many years and
>always rates as one of the best.

    To the best of my knowledge they are not identical but rather work identically.

JD - www.puresilver.org
 
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