Photo Forum / Film Photography / Darkroom / April 2004
Alternatives to Brown Plastic Jugs
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SofaKing - 08 Apr 2004 15:17 GMT My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel it's a little much for 25 cents worth of plastic. Are they magic or something. Couldn't I use rinsed out antifreeze jugs or windshield washer jugs? Do they have to be opaque? Thx.
Mark in Maine - 08 Apr 2004 15:33 GMT >My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel >it's a little much for 25 cents worth of plastic. Are they magic or >something. Couldn't I use rinsed out antifreeze jugs or windshield washer >jugs? Do they have to be opaque? Thx. A few thoughts:
In my case, I have a permanent darkroom, the lights are on in there during setup, but when it is unused, or when I am working, it is dark in there - so dark bottles are probably not all that important since the room is dark almost all the time.
Having said that - I use a lot of little bottles - for example - I use HC-110 as my main film developer - I dilute the syrup into the stock solution strength, then put it into 2oz bottles - brown glass, which I buy in bulk and they are not expensive (about $0.30 each?). To get the working solution, I mix one entire bottle with the appropriate amount of water.
I do a similar thing with Kodak HCA, Dektol, etc, using 2oz, 4oz and 8oz bottles as is appropriate so that for each working session I use a small number of bottles and never use a partial bottle. Since the bottles are full, there is little air in them, and I suspect that the stock solutions might last longer - but I have no data on this.
The main chemical that I do not use as one shot is fixer - this is because disposal of it in my case is a PITA, so I use it to exhaustion. For fixer, I use brown glass 1gal jugs. Don't remember what the 1 Gal jugs cost, but I don't think that they were as much as the plastic ones that you are looking at.
If I recall correctly, the type of bottles that I use, which can be found at scientific supply houses are referred to as 'Boston Round' or something like that - I have found two different types of caps for these - ones with plastic cone shaped liners, and ones with cardboard liners - I prefer the plastic cone ones since they hold up better and probably retain fewer chemicals on them.
Mark
PSsquare - 08 Apr 2004 15:59 GMT > Having said that - I use a lot of little bottles - for example - I use > HC-110 as my main film developer - I dilute the syrup into the stock > solution strength, then put it into 2oz bottles - brown glass, which I > buy in bulk and they are not expensive (about $0.30 each?). To get > the working solution, I mix one entire bottle with the appropriate > amount of water. \Mark,
Mark,
Nice to see a discussion of darkroom practice in the newsgroup. Now, on to the subject.
Check out this link: http://www.covingtoninnovations.com/hc110/
This presents an alternative to making the first dilution of HC110 and avoids any aging of the stock solution. My darkroom instructor recommended it and I have found it very practical. I simply go directly from syrup to final dilution using 16.1 ml of HC110 in 485 ml of filtered water. I measure the syrup in a 50 ml glass graduated cylinder, so I am accurate to around plus/minus .15 ml. After measuring the syrup, I add around 10 ml of water, cap it with my thumb (wearing a protective glove) and shake it before putting it in the final bottle. I rinse several more times thru the cylinder so that I am sure to get residual syrup into the mix. I put mix my solution in a 500ml water bottle so there is little error and no real measurement of the water; just fill the bottle to a mark on the neck that equals 16.1 plus 485 ml of solution. Seems close enough since .15 ml is around 2%. Any error in measurement is likely less important than degradation of the developer activity. Use the solution once and discard. No issue of storing at all.
Also, I have found that the simple 1 liter pop bottles are perfect for my 8x10 trays. Everything is stored in a cabinet in a room that is normally dark anyhow. So light exposure is at the absolute minimum.
Regards,
PSsquare
Mike - 08 Apr 2004 16:13 GMT > This presents an alternative to making the first dilution of HC110 and > avoids any aging of the stock solution. My darkroom instructor recommended [quoted text clipped - 11 lines] > degradation of the developer activity. Use the solution once and discard. > No issue of storing at all. Seems like more effort than I use for mixing HC110 directly from the syrup. I use a 5mL medicine dropper that my local Target pharmacy gave me for free. I draw 7.5mL (yes, it takes 2 draws) and squirt it into 240mL of water. I don't even bother with gloves.
Why mix twice?
BertS - 09 Apr 2004 23:48 GMT >>Having said that - I use a lot of little bottles - for example - I use >>HC-110 as my main film developer - I dilute the syrup into the stock [quoted text clipped - 35 lines] > > PSsquare I use a syringe, draw the amount of HC110 I need, stick the end of the syringe in the water and pressure it out. Then I draw in some of the water, pressure it out to rince the inside of the syringe. A bit of stirring afterwards does the trick.
Bert
BertS - 09 Apr 2004 23:43 GMT >>My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel >>it's a little much for 25 cents worth of plastic. Are they magic or [quoted text clipped - 33 lines] > liners - I prefer the plastic cone ones since they hold up better and > probably retain fewer chemicals on them. Those cones can be removed so you can rinse behind them. Just in case some chemicals got in and you swapped caps with something different.
A jeweler's screwdriver will slide into the edge and you can pry them out.
Bert
Dan Quinn - 10 Apr 2004 05:41 GMT > > If I recall correctly, the type of bottles that I use, which can be > > found at scientific supply houses are referred to as 'Boston Round' or > > something like that - I have found two different types of caps for > > these - ones with plastic cone shaped liners, and ones with cardboard > > liners - I prefer the plastic cone ones since they hold up better and > > probably retain fewer chemicals on them.
> Those cones can be removed so you can rinse behind them. Just in case some > chemicals got in and you swapped caps with something different. > > A jeweler's screwdriver will slide into the edge and you can pry them out. > > Bert I've come across two brands, Polycone and Polyseal. My entire mass of amber glass Boston Rounds have one or the other of those caps. Do not overfill. I use the cap ledge as a guide. The cone is forced into the neck of the bottle. I dry the bottle top then the cap goes on. They are rinsed prior to reuse. The cone mimics a rubber stopper and is held in contact by the screw cap. I can't think of a more sure way to seal a bottle. Also they may be reused many times. Tri Ess Sciences is a source for the above as well as other gear and chemistry. They do sell just caps. www.tri-esssciences.com Dan
Mark A - 08 Apr 2004 15:37 GMT > My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. Spend a few bucks and get some glass jugs. http://www.specialtybottle.com/
jjs - 08 Apr 2004 15:43 GMT > My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. If you don't mind semi-transparent plastic, then 1-gallon bottles with caps can be had new for between $1 to $3 each. Check out <http://www.usplastic.com>. Try searching on "industrial jugs". Their delivery service is very fast.
But what we could really use here is some true expert input from a plastics engineer. Plastic technology is a mystery. Some plastics let oxygen flow through, some let hydrocarbons pass, some are dark looking but are not really opaque to light. What's best for chemicals? In our lab we have some true light-opaque chemistry bottles that cost as much as $60 for a quart size.
David Nebenzahl - 08 Apr 2004 17:39 GMT On 4/8/2004 7:43 AM jjs spake thus:
>> My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel >> it's a little much for 25 cents worth of plastic. Are they magic or [quoted text clipped - 10 lines] > oxygen flow through, some let hydrocarbons pass, some are dark looking but > are not really opaque to light. What's best for chemicals? Perhaps you missed my post on this very question in another thread ("Rodinal"). Here's the gist of it:
> From his page on plastic bottles ["he" being someone named "Ryuji"] > (http://silvergrain.org/Photo-Tech/plastic.html): [quoted text clipped - 26 lines] > still alive and as vigorous in filled and tightly capped 500ml PET bottles > after two years! And as someone else pointed out, the best is still glass (assuming a good tight seal of some non-permeable material).
 Signature ... but never have I encountered a guy who could not be bothered to make his own case on his own show.
- Eric Alterman on his appearance on Dennis Miller's bomb of a show on CNBC (3/17/04)
John - 08 Apr 2004 15:47 GMT >My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel >it's a little much for 25 cents worth of plastic. Are they magic or >something. Couldn't I use rinsed out antifreeze jugs or windshield washer >jugs? Do they have to be opaque? Thx. Use soda bottles (PET) properly labels and store them in a cabinet.
Also, consider purchasing via mail order.
http://www.specialtybottle.com/store.asp
Regards,
John S. Douglas, Photographer - http://www.darkroompro.com Please remove the "_" when replying via email
Patrick Gainer - 08 Apr 2004 16:14 GMT > >My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > >it's a little much for 25 cents worth of plastic. Are they magic or [quoted text clipped - 9 lines] > > Regards, Drink lots of prune juice. It comes in nice wide mouthed brown bottles of various sizes.
> John S. Douglas, Photographer - http://www.darkroompro.com > Please remove the "_" when replying via email John - 08 Apr 2004 17:06 GMT >> Use soda bottles (PET) properly labels and store them in a >> cabinet. [quoted text clipped - 5 lines] >Drink lots of prune juice. It comes in nice wide mouthed brown bottles >of various sizes. And it just might help out the conversation on this group !
Regards,
John S. Douglas, Photographer - http://www.darkroompro.com Please remove the "_" when replying via email
lloydNO@NOthe-wire.com - 10 Apr 2004 14:05 GMT ...
> And it just might help out the conversation on this group ! ...
apr1004 from Lloyd Erlick,
But maybe not the subject matter!!
For chemical solution storage, I like Pepsi bottles. One liter, PETE plastic, wide mouth, a plastic-lined screw cap made to contain contents under gas pressure. Zero cost. Clear vs colored bottles is a non-issue if they spend most of their time in a cabinet or darkened room. Clear is preferrable because it permits examination of the contents.
Things like jugs and funnels and the like are better purchased from non-photo outlets. The nine dollar plastic jugs are a good illustration of why.
regards, --le
Nicholas O. Lindan - 08 Apr 2004 16:24 GMT > My local photo place wants $9 a pop for those 1 gal. chemical jugs! Cute, isn't it? Check out the price of an empty spray bottle at the hardware store - $3.00 - compared to the same bottle filled with Windex - $1.50.
Chemical jugs are made from thicker PE plastic than milk-jugs. I have found the best equivalent to be Minute-Maid Orange Juice jugs at $5.00 each when filled with rather good orange juice.
As other's have mentioned, 1 liter/quart PETE soda bottles are also suitable as PETE is reasonably gas impermeable. And splitting a gallon of solution into smaller lots makes it last a lot longer.
My favorite, though, is the Cubitaner: http://bestcontainers.com/hedpak---cubitainer-cubitainer--combination-packaging.html Dektol stock keeps for a year (when made with boiled distilled water; stirred, not shaken).
Do-it-yourself cubitainers can be made from the cartons and aluminized Mylar bags from wine-in-a-box (don't even think of drinking the wine, it's uniformly awful).
 Signature Nicholas O. Lindan, Cleveland, Ohio nolindan@ix.netcom.com Consulting Engineer: Electronics; Informatics; Photonics. psst.. want to buy an f-stop timer? nolindan.com/da/fstop/
Dan Quinn - 08 Apr 2004 22:08 GMT > My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. I can't think of any good reason why anybody would want or need to use gallon size anything for keeping darkroom chemicals. Just in case somebody else has thought of at least one good reason, I suggest the gallon jugs in which distilled water is packaged. For 79 cents I've a jug and one gallon of distilled water. Purely a technicality: Volumn goes up by a power of three while surface area by a power of two. In brief, the low surface area to volumn ratio of large containers favors longer chemical life. That is with all things being equall which is far from being the case. From Google enter, Tri Ess Sciences . They have a large selection of bottles, jugs, and jars. Also they have a variety of caps, including Polycone, and lids. Dan
Peter Irwin - 09 Apr 2004 01:33 GMT > I can't think of any good reason why anybody would want or need > to use gallon size anything for keeping darkroom chemicals. I keep Dektol in a one gallon brown glass jug. I usually get to the bottom before it gets seriously brown. I keep stock HCA in a four litre plastic jug which used to contain vinegar. I do the same with dilute photo-flo. Everything else goes in smaller bottles.
One good idea is to make sure that developer and fixer are kept in very different looking bottles. Everything should have labels on it too, but just having recognisible bottles reduces the chance of error.
Plastic pop bottles with plastic caps are good. Glass bottles with plastic caps are very good.
Peter.
 Signature pirwin@ktb.net
10x@_telus.net - 09 Apr 2004 02:26 GMT >> I can't think of any good reason why anybody would want or need >> to use gallon size anything for keeping darkroom chemicals. [quoted text clipped - 3 lines] >a four litre plastic jug which used to contain vinegar. I do the >same with dilute photo-flo. Everything else goes in smaller bottles. I have found the best containers yet to keep Dektol fresh are the four litre mylar wine bags sold by wine making stores. Mix the chemical, put it in the bag, make sure as much air as possible is removed -easy to do. I have found a bag of dektol stock solution in the back of a closet that was over three years old. It still hadn't turned brown and it still gave very good results when diluted 1:1
Take the " _ " out of 10x@_telus.net to reply
doug - 08 Apr 2004 23:37 GMT "SofaKing" wrote in message
> My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. Years ago I wandered into a shop that catered to home brewers (make your own wine & beer). They sold a variety of sized brown glass bottles and a nice assortment of caps for really cheap $. You may have bottles like them - they have the glass fingerhole at the top of the neck. They ranged in size from 30 oz. up to 160 oz. Of course they were all used. With a little washing they've become my alternative to the damned expensive brown plastic jugs.
Doug
Nick Zentena - 09 Apr 2004 00:07 GMT > "SofaKing" wrote in message >> My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel [quoted text clipped - 9 lines] > washing they've become my alternative to the damned expensive brown plastic > jugs. Any good homebrew place should be able to get new glassware. The other choice is to go to the supermarket and walk around. By the time you've walked up and down the aisles you might have found a bottle in the right size for very little money. Of course you need to dump out whats in it.
Nick
David Nebenzahl - 09 Apr 2004 07:51 GMT On 4/8/2004 4:07 PM Nick Zentena spake thus:
>> "SofaKing" wrote in message > [quoted text clipped - 15 lines] > walked up and down the aisles you might have found a bottle in the right > size for very little money. Of course you need to dump out whats in it. Maybe not available at just any supermarket, but those fancy-schmancy beer bottles with the built-in stopper with wire clamp are pretty good, too. I remember they used to hold Grolsch. Drink the beer, then store your stuff in them.
 Signature ... but never have I encountered a guy who could not be bothered to make his own case on his own show.
- Eric Alterman on his appearance on Dennis Miller's bomb of a show on CNBC (3/17/04)
John - 09 Apr 2004 08:07 GMT > Any good homebrew place should be able to get new glassware. The other >choice is to go to the supermarket and walk around. By the time you've >walked up and down the aisles you might have found a bottle in the right >size for very little money. Of course you need to dump out whats in it. I did that with bottles of imitation vanilla when it went on sale for $.75/bottle and I simply poured the vanilla into a soda bottle ;>)
Regards,
John S. Douglas, Photographer - http://www.darkroompro.com Please remove the "_" when replying via email
Dr. Dagor - 10 Apr 2004 00:07 GMT > My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. Air (specifically O2) is probably a bigger concern than light. And gallon is a large quantity. Even if you make developer in gallon units you are better off with smaller bottles -- quart or liter. If you fill them right to the top, the oxidization is minimized and your chemicals will last longer.
Dark quart bottles are what things like Hydrogen Peroxide come in. Just about any pharmacy has empty brown bottles in that size they will sell you.
Here's another trick... The dusters you can buy at any office supply store contain a heavier than air chemical that is pretty much inert to photochemicals. If you put a couple of puffs of that stuff in the bottle, it acts as a float and keeps the bad old air away from the good old chemicals.
jjs - 10 Apr 2004 00:56 GMT
> Air (specifically O2) is probably a bigger concern than light. And > gallon is a large quantity. Even if you make developer in gallon > units you are better off with smaller bottles [...] Ya know, it has been a hard week and I'm tired so I'll quibble before signing off to a good sleep. If (IF) you are using glass (or a plastic that doesn't admit oxygen), then what you speak of is all about surface area exposed to air - the amount of surface compared to total volume. Man, just fill the bottle to the top. Big containers are a Good Thing to the person who uses them. Can't say for those who mix it up and leave it a year, but why should we care?
David Nebenzahl - 10 Apr 2004 04:41 GMT On 4/9/2004 4:56 PM jjs spake thus:
> >> Air (specifically O2) is probably a bigger concern than light. And [quoted text clipped - 5 lines] > that doesn't admit oxygen), then what you speak of is all about surface > area exposed to air - the amount of surface compared to total volume. No need to quibble about it: you're right and he's wrong. As Dan Quinn pointed out somewheres up above here, volume increases faster than surface area, so the bigger, the bettah. Simple math, dontcha know.
 Signature ... but never have I encountered a guy who could not be bothered to make his own case on his own show.
- Eric Alterman on his appearance on Dennis Miller's bomb of a show on CNBC (3/17/04)
ericm1600@yahoo.com - 11 Apr 2004 00:05 GMT >If (IF) you are using glass (or a plastic >that doesn't admit oxygen), then what you speak of is all about surface >area exposed to air - the amount of surface compared to total volume. Man, >just fill the bottle to the top. Big containers are a Good Thing to the >person who uses them. Can't say for those who mix it up and leave it a >year, but why should we care? If the choice is between several small, half full containers vs. one large half full container, you're right. The larger container wins.
If the choice is between several small, completely full containers plus one small container with a variable amount vs. one large, variably full container, the former will be better.
Like you said, it's all about exposed surface area. Keep your containers completely full for longest life. It doesn't really matter whether you do this by using small containers one by one or dropping marbles into a larger one. It's about minimizing air contact with surface area.
-- Eric http://canid.com/
Dan Quinn - 11 Apr 2004 23:33 GMT Dr. Dagor) wrote:
> > > Air (specifically O2) is probably a bigger concern than light. And [quoted text clipped - 8 lines] > person who uses them. Can't say for those who mix it up and leave it a > year, but why should we care? A very important point is being overlooked. IF, the bottle material is entirely impermeable to air, if it is full, and if it is sealed, THEN the surface area to volumn ratio is of no consequence. I think most would agree that glass is the last word where impermeability is concerned. I use glass, so big or small bottle, I worry not. The less so because I use caps which SEAL. I'll restate that. The aging of chemistry due to air finding it's way through glass into the bottles is out of the question. I do check and recheck the cap to be sure the slightly resilient cone is snug whithin the neck of the bottle.
A few words about oxygen. There is'nt very much of it. I doubt a 2.54 centimeter cube of air would keep a flea breathing more than a few minutes. SEALED, impermeable bottles are an oxygen hungry solution's best insurace. Dan
jjs - 11 Apr 2004 23:58 GMT > [...] > A few words about oxygen. There is'nt very much of it. I doubt > a 2.54 centimeter cube of air would keep a flea breathing more than > a few minutes. SEALED, impermeable bottles are an oxygen hungry > solution's best insurace. Now we will have people floating a flea in the top of the bottle.
Patrick Gainer - 15 Apr 2004 16:53 GMT > > My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > > it's a little much for 25 cents worth of plastic. Are they magic or [quoted text clipped - 16 lines] > bottle, it acts as a float and keeps the bad old air away from the > good old chemicals. The amount of air that is in the water you use to mix your solutions may be enough to reduce considerably the capacity of your developer. This is especially true of ascorbate developers. 0.09 grams of oxygen will oxidize 1 gram of ascorbic acid, and sulfite will not prevent it. Neither will storage at low pH. The oxygen scavenging power of ascorbic acid not only works at pH of about 3, but the products of oxidation are also acidic. 1 gram of ascorbic acid is also capable of reducing enough silver halide to produce an average density of 1 on 38 rolls of film or 8X10 sheets, so 0.09 grams of oxygen may reduce your developer's capacity by 38 rolls of film. The point is that keeping oxygen from entering the solution after mixing may not be enough. A way to scavenge all oxygen from the solution right from the start is needed.
Dan Quinn - 16 Apr 2004 09:23 GMT > The amount of air that is in the water... (that would be .00845 grams of oxygen at saturation per liter)
> ...you use to mix your solutions > may be enough to reduce considerably the capacity of your developer. > This is especially true of ascorbate developers. 0.09 grams of oxygen > will oxidize 1 gram of ascorbic acid, That be the case 1/10th of that gram will be oxidized when placed in one liter of oxygen saturated water or 1/100 will be oxidized if ten grams be placed in the same water.
> and sulfite will not prevent it. > Neither will storage at low pH. The two togeather will preserve ascorbic acid if the solution ph is below 5.5.
> 1 gram of ascorbic acid is also capable of reducing enough > silver halide to produce an average density of 1 on 38 rolls of film > or 8X10 sheets, ... I've real doubts about that. I've not actually put 38 rolls or that many 8x10s through a developer with no more than one gram of ascorbic acid as the developing agent. In fact I don't even consider ascorbic acid a developing agent. If the ph is way way up it will reduce some silver. I think it is best likend to hydroquinone for it's regenerative function. That is it reduces the other or other developing agent/agents present.
> A way to scavenge > all oxygen from the solution right from the start is needed. For most solutions I'd consider that more ado about nearly nothing. Some very dilute solutions should be striped of that .00845 gram of oxygen. The usuall way to scavange that O2 is a pinch of sulfite first than the whatever. For ascorbic acid try the bisulfite. I've found the two to be harmonious. Stirring of solutions which are subject to oxidation must be minimized. Dan
Patrick Gainer - 16 Apr 2004 17:45 GMT > > The amount of air that is in the water... > [quoted text clipped - 22 lines] > that many 8x10s through a developer with no more than one gram of > ascorbic acid as the developing agent. It wouldn't make any difference if you had 10 grams of ascorbic acid. 1 of those grams is still used up by 38 rolls of film. None of the phenidone or metol is used up. So which is the developing agent? The phenidone alone will certainly not do that.
> In fact I don't even consider ascorbic acid a developing agent. If > the ph is way way up it will reduce some silver. I think it is best > likend to hydroquinone for it's regenerative function. That is > it reduces the other or other developing agent/agents present. You can look at it that way if you want, but it is wrong. It is not proper to consider the ascorbic acid or hydroquinone as only regenerating the phenidone. The phenidone or metol activates the hydroquinone or ascorbate, which do the actual work. In the case of ascorbates, the product of reaction with any so-called "free radical" is dehydroascorbic acid. The developer solution becomes more acidic as development of silver halide progesses. It also becomes more acidic as oxygen is converted to water by the two hydrogen atoms it gets from ascorbic acid or any ascorbate. This occurs at pH of 3 or so and higher. How much ascorbate is in Xtol diluted 1+2?
Sulfite is required for the synergism between hydroquinone and other agents, as one of the intermediate products is hydroquinone monosulfonate. Sulfit is not required for the synergism between ascorbates and othe agents. The mechanism is not the same as for hydroquinone.
I think the solubility of oxygen in water is greater than 0.09 grams/liter. The amount of silver needed to cover a given area to a given optical or photographic density is well known for old emulsions. It is probably even less for the tabular grained ones. 0.0001 grams of silver per cm square per unit density is a conservative number for the calculations I did. 1 molecular weight of ascorbic acid will be oxidized to dehydroascorbic acid by 1 atomic weight of oxygen. If there are any other things in the water, such as bacteria, they may as well oxidize some ascorbate. Iron is known to catalyze the oxidation process.
The easiest way to avoid some of these real or imagined problems that I have found is to keep the stock solution inactive until you want to develop film by dissolving it in a glycol.
> > A way to scavenge > > all oxygen from the solution right from the start is needed. [quoted text clipped - 7 lines] > Stirring of solutions which are subject to oxidation must be > minimized. Dan Patrick Gainer - 16 Apr 2004 21:21 GMT > > > The amount of air that is in the water... > > [quoted text clipped - 74 lines] > > Stirring of solutions which are subject to oxidation must be > > minimized. Dan Sorry. One of the hazards of the slide rule is decimal point errors. I think the solubility of oxygen in cold water is about 4.5 cc per liter. That would be about 0.009 grams at atmospheric pressure.
I don't want to use any sulfite in my ascorbate developers, for other reasons. Perhaps a tiny bit of hydroquinone would be a more appropriate scavenger than sulfite, since it has practically no developing power of its own at low pH and low concentration, and is not superadditive with either ascorbic acid or phenidone without sulfite. Better yet, a tiny bit of pyro. But that would increase the hazard slightly, enough to scare off many people.
Dan Quinn - 17 Apr 2004 23:24 GMT > > (that would be .00845 grams of oxygen at saturation per liter) NOT COLD but 20*C
> > The two togeather will preserve ascorbic acid if the solution ph > > is below 5.5. Bisulfite and a low ph. That is according to the book. I've some mixed up and now ageing. I'll likely test again in a few weeks.
> > In fact I don't even consider ascorbic acid a developing agent. If > > the ph is way way up it will reduce some silver. I think it is best > > likend to hydroquinone for it's regenerative function. That is > > it reduces the other or other developing agent/agents present.
> The phenidone or metol activates the > hydroquinone or ascorbate, which do the actual work. THAT will be news to quite a few! Dan
> > > A way to scavenge > > > all oxygen from the solution right from the start is needed. [quoted text clipped - 7 lines] > > Stirring of solutions which are subject to oxidation must be > > minimized. Dan Patrick Gainer - 18 Apr 2004 21:34 GMT > > > (that would be .00845 grams of oxygen at saturation per liter) > NOT COLD but 20*C [quoted text clipped - 4 lines] > That is according to the book. I've some mixed up and now ageing. > I'll likely test again in a few weeks. Which book?
> > > In fact I don't even consider ascorbic acid a developing agent. If > > > the ph is way way up it will reduce some silver. I think it is best [quoted text clipped - 5 lines] > > THAT will be news to quite a few! But not to the authors of "Theory of the Photographic Science" Pat
> > > > A way to scavenge > > > > all oxygen from the solution right from the start is needed. [quoted text clipped - 7 lines] > > > Stirring of solutions which are subject to oxidation must be > > > minimized. Dan Dan Quinn - 19 Apr 2004 11:06 GMT > > The two togeather will preserve ascorbic acid if the solution ph > > is below 5.5. [quoted text clipped - 3 lines] > > I'll likely test again in a few weeks. > > Dan
> Which book? In a manor of speaking, a book. I found that information via Google. The paper dealt, IIRC, with various anti-oxidates used with pharmaceuticals. I'll see if I can find it. Dan
Patrick Gainer - 19 Apr 2004 17:00 GMT > > > The two togeather will preserve ascorbic acid if the solution ph > > > is below 5.5. [quoted text clipped - 9 lines] > Google. The paper dealt, IIRC, with various anti-oxidates used with > pharmaceuticals. I'll see if I can find it. Dan I should have said my idea of ascorbic acid as a developing agent would not be surprising to the authors "Theory of the Photographic Process." This what happens when I trust my 76 yeaar old memory. I believe in the hereafter. When I set out to get something, I get where I think it is, but cannot remember what I am here after
Dan Quinn - 27 Apr 2004 11:41 GMT > > Dan Quinn wrote: > > [quoted text clipped - 4 lines] > > Which book? I've yet to find that article. I may have made an error. A ph of 5.5 may be the equallibrian ph. BTW, have you tested ascorbic by itself for keeping qualities? With it's ph in solution well below 3, I think it might do well. I've some in Polycone sealed glass bottles and intend to test it. Dan
Norman Worth - 11 Apr 2004 00:25 GMT Shop around. Chemical supply houses sell quality plastic ware at a quite a bit less. Some of the bigger photo mail order places do too. If I don't need the brown color (usually I don't), I've been using 2 liter soft drink bottles. They are impermeable to air (unlike LD polyethylene), convenient, and extremely cheap, but you may have to replace them a bit more often.
> My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel > it's a little much for 25 cents worth of plastic. Are they magic or > something. Couldn't I use rinsed out antifreeze jugs or windshield washer > jugs? Do they have to be opaque? Thx. lloydNO@NOthe-wire.com - 12 Apr 2004 14:11 GMT >My local photo place wants $9 a pop for those 1 gal. chemical jugs! I feel >it's a little much for 25 cents worth of plastic. Are they magic or >something. Couldn't I use rinsed out antifreeze jugs or windshield washer >jugs? Do they have to be opaque? Thx. apr1204 from Lloyd Erlick,
I think the whole issue of light having an effect on darkroom solutions is academic. Whether a container is clear, brown or opaque has little practical effect in a usual darkroom.
Direct sunlight would be of most consequence to chemical soultions. Direct, bright daylight would be next. Interior, artificial lighting would be the least degrading light (well, next to safelight...). The energy content of the light is the issue. (Don't put your grow op in the darkroom!)
Most darkrooms are dark most of the time. If solutions are stored in clear glass bottles in a cabinet or under a sink, in a room that is mostly dark, and lit by artificial light when it is not dark, I'd say the degradation of chemistry by light would be too slight to consider. Much better to control oxygen degradation.
I like clear containers because I can take a good look at my solutions, and especially because I can monitor the condition of my containers...
Over the years I have gone from using gallon, or larger, jugs, to a multiplicity of small bottles suitable for one shot processing, to very nearly no storage of liquid chemistry at all.
I like to measure out dry chemicals and mix directly to a working solution.
But of course, once I've mixed and used my working solution of Ansco 120 print developer (the D23 of prints...) the temptation to store and re-use is sometimes overwhelming. So I put it in a clear bottle, and refrain from putting a label on it. If I can't remember what it is or how old it is, it is too old. I find 120 does fairly well after twenty-four hours, even forty-eight. But I think making it with distilled water is far more important than storing it in a brown container.
Some chemicals take a while to dissolve, so per cent solutions have to be stored. EDTA is a good example. I don't worry about light harming my EDTA in its clear bottle (made of PETE plastic). I make ten per cent solutions of potassium bromide (and keep it in clear PETE), but not because it's hard to dissolve -- it absorbs moisture from the air so readily that the contents of the (brown glass!) storage bottle cake up if it's opened too often. So I open it around four times over its lifetime to make my per cent solutions. (Actually, now I think of it, Kodak sells potasium bromide in polyethylene now. My rapidly seniorizing memory shows it surprisingly clearly in brown glass...).
A very good source of containers for the darkroom is -- the garbage. Restaurant dumpsters supply lots of very heavy duty plastic pails and lids, in sizes from a few liters to twenty liters, both air/water-tight and less tight. Stay away from any that held greasy stuff. Pails that held fruit salad clean rapidly. (Seeing the size of those pails puts me right off fruit salad, perhaps not very logically.) I've got several twenty liter pails that originally held dill pickles. They cleaned up in a moment, but the smell of garlic pickles held on for months.
Any kind of chemically based photo or cinema film processing plant will throw away many types of containers and closures, in amazingly large quantities. Glass jugs and cubitainers that held distilled water are the best because they require little or no cleaning.
I used to work in a welfare emergency hostel, which discarded 125 ml brown glass bottles that came filled with children's cough syrup. They went through them at a furious rate. There was a product called 'grippe water' that was given to babies. The darkroomie in me compels me to read the label on every damn thing I get in my hands. Grippe water was five per cent alcohol. None of the "toxics" in the darkroom, powder, liquid or gas, smelly or insidious, comes close to offending me as much as giving alcohol to infants.
It's not necessary to pay nine dollars for a plastic container. It's possible to pay zero, or to buy much superior glass containers for less than that. In fact, the obnoxious, combative darkroomie in me says any photo shop that tries to sell nine dollar (would those be US dollars?) plastic jugs does not merit patronage.
Same goes for overpriced plastic funnels! (Cut the bottom off a two liter PETE soft drink bottle, turn it upside down, and -- there is a funnel.)
regards, --le
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