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Photo Forum / Film Photography / Darkroom / February 2004

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sodium metaborate

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Hi - 20 Feb 2004 02:14 GMT
http://www.colba.net/~fotochem/index.htm  for sodium metaborate
Patrick Gainer - 20 Feb 2004 03:44 GMT
> http://www.colba.net/~fotochem/index.htm  for sodium metaborate
69 grams of 20 Mule Team borax +14.5 grams of Red Devil lye in a liter
of solution is close enough to a 10% solution of Kodalk for government
work. Kodalk is sodiun metaborate tetrahydrate. The reason the
ingredients do not add to 100 grams is the 4 molecules of water that are
present in Kodalk but not in the borax-lye combination, among other
things.
Nick Zentena - 20 Feb 2004 04:04 GMT
>> http://www.colba.net/~fotochem/index.htm  for sodium metaborate
> 69 grams of 20 Mule Team borax +14.5 grams of Red Devil lye in a liter
[quoted text clipped - 3 lines]
> present in Kodalk but not in the borax-lye combination, among other
> things.

 I don't remember what I paid for borax the last time but I don't think it
was much cheaper then buying metaborate in the 5lb bag.

   Nick
Lloyd Erlick - 20 Feb 2004 14:19 GMT
>...
>  I don't remember what I paid for borax the last time but I don't think it
>was much cheaper then buying metaborate in the 5lb bag.
>
>    Nick

feb2004 from Lloyd Erlick,

Correct me if I'm wrong (haven't used Kodalk in
some time) but I think the problem with having
large amounts of it around is that it cakes in
storage unless carefully handled. Five pounds
might be hard to keep in useable condition.

regards,
--le
________________________________
Lloyd Erlick Portraits,
2219 Gerrard Street East, unit #1,
Toronto M4E 2C8 Canada.
                ---
voice 416-686-0326
lloyd AT the-wire DOT com
http://www.heylloyd.com
________________________________
Nick Zentena - 20 Feb 2004 16:12 GMT
>>...
>>  I don't remember what I paid for borax the last time but I don't think it
[quoted text clipped - 9 lines]
> storage unless carefully handled. Five pounds
> might be hard to keep in useable condition.

 I don't remember what shape mine is in. I only use it for TF-2 fixer and
that's a massive 10 grams per litre. Wouldn't a mortar be enough to fix
things?

    Nick
Jean-David Beyer - 20 Feb 2004 20:49 GMT
>> ... I don't remember what I paid for borax the last time but I
>> don't think it was much cheaper then buying metaborate in the 5lb
[quoted text clipped - 8 lines]
> cakes in storage unless carefully handled. Five pounds might be hard
> to keep in useable condition.

Perhaps it depends on how you store it. I keep it in either glass jars,
or in metal "paint-cans" and never have problems storing it.

I am always bemused by people wanting to make up sodium metaborate from
borax and sodium hydroxide, making stop bath from vinager, and so on.
Perhaps this may be necessary in some out of the way outposts, but in
most countries of the civilized world (i.e., wherever fine chemicals are
sold), you should be able to get what you need except for very rare
things, and these things are not rare.

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Nicholas O. Lindan - 20 Feb 2004 21:04 GMT
> I am always bemused by people wanting to make up sodium metaborate ...
> stop bath from vinegar, and so on ... in most countries of the
> civilized world ... you should be able to get what you need

It just doesn't take much to bemuse some folks.

Maybe in Civilized Shrewsbury they have a Midnight Chemical Supply,
but here in Decadent Cleveland I use the local grocery store --
for Calgon, borax, carbonate, ascorbic acid, acetic acid, sodium
sulfite, blah-blah-blah -- and when I need something at odd hours,
they are always open.

Another reason: I already have a cupboard full of chemicals.  Why
stuff it full of more chemicals (that can't be used for anything
else [is metaborate a base stock for anything?] and will probably
solidify, leak or go off before I finish the jar) when I can do it
myself if 2 minutes?

I am in favor of stocking just the basics.

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Nicholas O. Lindan, Cleveland, Ohio nolindan@ix.netcom.com
Consulting Engineer:  Electronics; Informatics; Photonics.

Jean-David Beyer - 20 Feb 2004 21:57 GMT
>>I am always bemused by people wanting to make up sodium metaborate ...
>>stop bath from vinegar, and so on ... in most countries of the
[quoted text clipped - 7 lines]
> sulfite, blah-blah-blah -- and when I need something at odd hours,
> they are always open.

Oh, no. We do not have a suitable chemical supply house at all. The
nearest is Fishkin Brothers in Perth Amboy, about 1/2 hour north of here
by train or automobile. And they are open only during business hours.

> Another reason: I already have a cupboard full of chemicals.  Why
> stuff it full of more chemicals (that can't be used for anything
> else [is metaborate a base stock for anything?]

F6 fixing bath, some developers, pre-toning bath.

> and will probably
> solidify, leak or go off before I finish the jar) when I can do it
> myself if 2 minutes?
>
> I am in favor of stocking just the basics.

I agree. We may differ in just what the basics might be.

For me, they include
Metol, Hydroquinone, Amidol (I could do without it)
Sodium Sulfite, Sodium Sulfate, Sodium metabisulphite
Borax (I could do without it), Sodium Metaborate,
Citric acid (I could do without it), Acetic acid
Sodium Thiosulphate (pentahydrated)
Benzotriazole, Potassium Bromide (I could do without it)
Potassium Alum
PhotoFlow, KRST

I have 5 pound bottles of most of those on a single 6' shelf.
The rest of them (the developing agents, the KBr, Sodium metabisulphite,
benzotriazole) are in smaller bottles. A special case is sodium
thiosulphate: I get a 100 pound drum of that stuff at a time. I know
when I am likely to run out, so I can get the next supply during normal
business hours.

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Jorge Omar - 20 Feb 2004 22:43 GMT
In the city I live there are many chemists.
The store I use the most sells sulfite, hydroquinone, phenidone,
carbonate, hypo, propylene glycol, acetic acid, a lot of things.
But no metol or metaborate in any store.
They say there's no demand for them in retail, and when the phenidone
stock is over, it'll be gone.

Jorge

> I am always bemused by people wanting to make up sodium metaborate
> from borax and sodium hydroxide, making stop bath from vinager, and so
> on. Perhaps this may be necessary in some out of the way outposts, but
> in most countries of the civilized world (i.e., wherever fine
> chemicals are sold), you should be able to get what you need except
> for very rare things, and these things are not rare.
Lew - 21 Feb 2004 00:16 GMT
...and for a chemically ignorant acolyte, how much of this 10% solution is
needed to add the equivalent of 1 gram of Kodalk to a solution? BTW,
congrats on the Photo Techniques article. Neat.
-Lew
Francis A. Miniter - 21 Feb 2004 00:22 GMT
Hi Lew,

Once you have a 10% solution of anything, then for every liter you have
100 grams of the chemical, in this case, Kodalk.  To get 1 gram of
Kodalk out of it, use 10 ml. of solution.

Francis A. Miniter

>...and for a chemically ignorant acolyte, how much of this 10% solution is
>needed to add the equivalent of 1 gram of Kodalk to a solution? BTW,
>congrats on the Photo Techniques article. Neat.
>-Lew
 
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